Prepare the White Chocolate Velvet Spray
Fill the basin of your chocolate spray gun with warm water to preheat it.
Combine the white chocolate and cocoa butter in a microwave-safe container.
Microwave in 15-second intervals, stirring between each, until completely melted and the mixture reaches 122°F (50°C).
Add orange oil-based food coloring, if desired, and blend until evenly incorporated. Do not use water-based coloring, which can cause the chocolate to seize.
Drain and thoroughly dry the spray gun basin.
Pour the melted chocolate mixture through a fine-mesh sieve into the basin, following your spray gun manufacturer's recommended operating temperature.
Spray the Frozen Pumpkins
Prepare a protected, well-ventilated spraying area.
Remove one fully frozen pumpkin from its mold. With my particular molds, I find it helpful to cup the bottom of the pumpkin in one hand and gently push upward while peeling back the top of the mold with the other. This helps release the pumpkin without accidentally leaving dents in its surface.
Working quickly, spray with a thin, even layer of chocolate velvet spray.
Return the pumpkin to a covered, freezer-safe container.
Repeat with the remaining pumpkins, working one at a time so each pumpkin is completely frozen when sprayed. Note: The velvet texture forms when tiny droplets of warm chocolate and cocoa butter solidify almost instantly on the frozen mousse. Use light passes rather than a thick coating to preserve the pumpkin details.